Web3 axes) of a silicon-centered cube., 3,4,19 cf. Figure 1. In addition, each body diagonal direction allows for an “up” and “down” alignment. Thus, the average crystallographic structure of α-ASiH 3 is based on eight (random) orientations for each SiH 3 − ion (Figure 1). At temperatures below 200 K, ASiH 3 compounds exist as hydrogen ... WebFeb 1, 2024 · Abstract The hydrogen storage materials ASiH 3 (A=K, Rb) represent complex metal hydrides built from metal cations and pyramidal SiH 3 - ions. At room temperature, SiH 3-moieties are randomly oriented because of dynamical disorder (α-modifications).At temperatures below 200 K, ASiH 3 exist as ordered low-temperature β modifications. …
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